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Field-free molecular alignment induced by elliptically polarized laser pulses: non invasive 3 dimensional characterization

机译:椭圆偏振激光诱导的无场分子排列   脉冲:非侵入性三维表征

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摘要

An investigation of field-free molecular alignment produced by ellipticallypolarized laser pulses is reported. Experiments are conducted in CO$_2$ at roomtemperature. A non invasive all-optical technique, based on the crossdefocusing of a probe pulse, is used to measure the alignment along twoorthogonal directions that is sufficient to provide a 3 dimensionalcharacterization. The field-free molecular alignment produced by a laser ofelliptical polarization is in good agreement in terms of amplitude and shapewith theoretical predictions. It turns out to be almost equivalent to thesuperposition of the effects that one would obtain with two individualcross-polarized pulses. The investigation highlights notably the occurrence offield-free two-direction alignment alternation for a suitably chosen degree ofellipticity. The analogy between this specific ellipticity and the well known"magic angle" used in time resolved spectroscopy to prevent rotationalcontributions is discussed.
机译:报道了对由椭圆偏振激光脉冲产生的无场分子排列的研究。实验在室温下以CO $ _2 $进行。基于探针脉冲的交叉散焦的非侵入性全光学技术用于测量沿正交方向的对齐,该对齐足以提供3D特征。椭圆偏振激光产生的无场分子排列在幅度和形状方面与理论预测非常吻合。事实证明,这几乎等同于两个单独的交叉极化脉冲所能获得的效果叠加。该研究尤其突出了在适当选择的椭圆度的情况下,无场的双向对准交替的发生。讨论了该特定椭圆率与时间分辨光谱法中用于防止旋转贡献的众所周知的“魔角”之间的类比。

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